You do not know what the slop is but you do know that the slope between any two points will be the same as between any other 2 points.
\(\frac{3--5}{-a+2-3}=\frac{2--5}{2a+3-3}\\ \frac{8}{-a-1}=\frac{7}{2a}\\~\\ 16a=-7a-7\\ 23a=-7\\ a=\frac{-7}{23} \)
check
\((3,-5),\quad (2\frac{7}{23},3),\quad (2\frac{9}{23},2)\)

LaTex:
\frac{3--5}{-a+2-3}=\frac{2--5}{2a+3-3}\\
\frac{8}{-a-1}=\frac{7}{2a}\\~\\
16a=-7a-7\\
23a=-7\\
a=\frac{-7}{23}