So when you do that. I've been staring at the code for a long time now but I GET IT :D.
You add rrlll instead of rrl and after qquad (before the brackets) you add an ampersand.
I've done it on the same post (first comment).
\begin{array}{rrlll}
33-2x&=&5-9x\qquad&(- 5)\\
28-2x&=&-9x\qquad&(+9x)\\
28+7x&=&0\qquad&(which\;means)\\
28&=&7x\qquad&(28\div7=4)\\
x&=&4\\
\end{array}